Volcán Descabezado Grande is a late-Pleistocene to Holocene andesitic-to-rhyodacitic stratovolcano with a 1.4-km-wide ice-filled summit crater. It lies at the center of a 20 x 30 km volcanic complex, 7 km N of the Cerro Azul stratovolcano. A lateral crater, which formed on the upper NNE flank in 1932 shortly after the end of the major 1932 eruption from nearby Quizapu cone on the N flank of Cerro Azul, was the site of the only recorded eruption. The Holocene Alto de las Mulas fissure on the lower NW flank produced young rhyodacitic lava flows. Numerous small late-Pleistocene to Holocene volcanic centers are located N of the volcano. The northernmost of these, Lengua de Vulcano (or Mondaca), produced a very youthful rhyodacitic lava flow that dammed the Río Lentué.